Reduction of Polymer Waste Pyrolysis Fractions over Pt/Al2O3with Methanol Decomposition Hydrogen to Obtain Fuel-Grade Hydrocarbons-Reference-Cited by-同舟云学术

Reduction of Polymer Waste Pyrolysis Fractions over Pt/Al2O3with Methanol Decomposition Hydrogen to Obtain Fuel-Grade Hydrocarbons

Published:2014 Issue: Volume:2014 Page:1-9
ISSN:2090-9063
Container-title:Journal of Chemistry
language:en
Short-container-title:Journal of Chemistry

Author:

Śmigiera Ewa¹^ORCID,Osawaru Osazuwa¹^ORCID,Kijeński Jacek¹²,Migdał Antoni¹,Zgudka Anna¹^ORCID

Affiliation:

1. Industrial Chemistry Research Institute, No. 8 Rydygiera Street, 01-793 Warsaw, Poland

2. Faculty of Civil Engineering, Mechanics and Petrochemistry, Warsaw University of Technology, No. 17 Łukasiewicza Street, 09-400 Płock, Poland

Abstract

The hydrogenation under atmospheric pressure of waste polymer pyrolysis fractions over 5% Pt/γ-Al2O3with hydrogen from the catalytic decomposition of methanol over 5% CoO/SiO2has been performed. A 97–100% C=C bond hydrogenation selectivity was achieved at 300°C. The obtained saturated C6–C20and C20–C30fractions can be applied as blending material for fuels and lubricants, respectively, or as hydrocarbon feed. The applied coupled catalytic system exhibited high efficiency at 300°C for at least 5 hours.

Funder

Polish Ministry of Science and Higher Education

Publisher

Hindawi Limited

Subject

General Chemistry

Link

http://downloads.hindawi.com/journals/jchem/2014/938696.pdf

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