Silver(I) Catalyzed Photochemical Oxidation of Methylene Blue and Safranine-O by Peroxydisulphate: A Green Chemical Approach

Author:

Chhajed Ravisha1,Sharma Sanyogita2,Ameta Rakshit3ORCID,Punjabi Pinki B.1

Affiliation:

1. Photochemistry and Solar Energy Laboratory, Department of Chemistry, College of Science, Mohanlal Sukhadia University, Udaipur 313002, India

2. Pacific Institute of Technology, Pacific Hills, Airport Road, Udaipur 313003, India

3. Pacific College of Basic & Applied Sciences, PAHER University, Udaipur 313003, India

Abstract

In the present investigation, a comparative study of silver(I) catalysed photochemical oxidation of methylene blue (MB) and safranine-O (SO) by peroxydisulphate has been reported. The effect of different parameters, such as pH, concentration of peroxydisulphate, silver nitrate, and light intensity, on the reaction rate has been observed. The progress of the photochemical oxidation was monitored spectrophotometrically. The optimum conditions for photochemical oxidation were achieved. The dyes were completely oxidized and degraded into CO2 and H2O. A tentative mechanism for silver(I) catalyzed photochemical oxidation of these dyes by peroxydisulphate has also been proposed.

Publisher

Hindawi Limited

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