Modification of Poly(vinyl chloride) by N-Phenyl Itaconimides for the Improvement of Its Thermal Stability

Author:

Elsharif Asma M.1ORCID,Al-Ghamdi Azza A.1,Abdel-Naby Abir S.1ORCID

Affiliation:

1. Chemistry Department, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, 31441 Dammam, Saudi Arabia

Abstract

Poly(vinyl chloride) (PVC) is modified by N-phenyl itaconimide derivatives (N-(RPh)IM) as modifying agents or graft comonomers. The resulting modified polymers or graft copolymers were characterized using FTIR and UV/Vis spectrophotometry. The thermal properties of the modified polymers were investigated using thermogravimetry (TGA), which revealed that the synthesized polymers exhibited high thermal stability, as shown from the value of their initial decomposition temperatures and the percentage of weight loss at high temperatures. The polymer modified by 4-bromo itaconimide exhibited the most thermal stability. A mechanism for the modification reaction and the graft copolymerization of PVC was suggested.

Funder

Imam Abdulrahman Bin Faisal University

Publisher

Hindawi Limited

Subject

General Chemistry

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