Nanocomposites of NR/SBR Blend Prepared by Latex Casting Method: Effects of Nano-TiO2 and Polystyrene-Encapsulated Nano-TiO2 on the Cure Characteristics, Physical Properties, and Morphology

Abstract

Nanocomposites of 80/20 (w/w) natural rubber (NR)/styrene butadiene rubber (SBR) blend with four loadings of either nanosized titanium dioxide (nTiO2) or polystyrene-encapsulated nTiO2 (PS-nTiO2), ranging from 3 to 9 parts by weight per hundred of rubber (phr), were prepared by latex casting method. The PS-nTiO2 synthesized via in situ differential microemulsion polymerization displayed a core-shell morphology (nTiO2 core and PS shell) with an average diameter of 42 nm. The cure characteristics (scorch time, cure time, and cure rate index), mechanical properties (tensile properties, tear strength, and hardness), thermal stability, glass transition temperature, and morphology of the prepared nanocomposites were quantified and compared. The results showed that the cure characteristics of all the nanocomposites were not significantly changed compared to those of the neat NR/SBR blend. The inclusion of an appropriate amount of either nTiO2 or PS-nTiO2 into the NR/SBR blend apparently improved the tensile strength, modulus at 300% strain, tear strength, hardness, and thermal stability but deteriorated the elongation at break of the nanocomposites. Based on differential scanning calorimetry, the glass transition temperature of all the nanocomposites was similar to that of the neat NR/SBR blend. Moreover, the morphology of the PS-nTiO2-filled rubber nanocomposites fractured surface analyzed by scanning electron microscopy showed an improvement in the interfacial adhesion between the rubber phase and the nanoparticles.