Removal of Chromium (III) from Water by Using Modified and Nonmodified Carbon Nanotubes

Author:

Atieh Muataz Ali12,Bakather Omer Yahya1,Tawabini Bassam S.3,Bukhari Alaadin A.4,Khaled Mazen5,Alharthi Mamdouh1,Fettouhi Mohammed5,Abuilaiwi Faraj Ahmad26

Affiliation:

1. Chemical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

2. Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

3. Earth Sciences Department, King Fahd University of Petroleum & Minerals, KFUPM P.O. Box 952, Dhahran 31261, Saudi Arabia

4. Center for Environment & Water, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

5. Chemistry Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia

6. Hafr Al-Batin Community College, King Fahd University of Petroleum & Minerals, Hafr Al-Batin 31991, Saudi Arabia

Abstract

This study was carried out to evaluate the environmental application of modified and nonmodified carbon nanotubes through the experiment removal of chromium trivalent (III) from water. The aim was to find the optimal condition of the chromium (III) removal from water under different treatment conditions of pH, adsorbent dosage, contact time and agitation speed. Multi wall carbon nanotubes (MW-CNTs) were characterized by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The diameter of the carbon nanotubes produced varied from 20–40 nm with average diameter of 24 nm and 10 micrometer in length. Adsorption isotherms were used to model the adsorption behavior and to calculate the adsorption capacity of the absorbents. The results showed that, 18% of chromium (III) removal was achieved using modified carbon nanotubes (M-CNTs) at pH 7, 150 rpm, and 2 hours for a dosage of 150 mg of CNTs. The removal of Cr (III) is mainly attributed to the affinity of chromium (III) to the physical and chemical properties of the CNTs. The adsorption isotherms plots were well fitted with experimental data.

Funder

King Abdulaziz City for Science and Technology

Publisher

Hindawi Limited

Subject

General Materials Science

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