Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst-Reference-Cited by-同舟云学术

Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Published:2020-01-24 Issue: Volume:2020 Page:1-11
ISSN:2090-9063
Container-title:Journal of Chemistry
language:en
Short-container-title:Journal of Chemistry

Author:

Aberkouks Abderrazak¹²,Mekkaoui Ayoub Abdelkader¹²^ORCID,Ait Ali Mustapha²,El Firdoussi Larbi²^ORCID,El Houssame Soufiane¹^ORCID

Affiliation:

1. Laboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, Morocco

2. Laboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, B. P. 2390, 40001 Marrakech, Morocco

Abstract

Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.

Publisher

Hindawi Limited

Subject

General Chemistry

Link

http://downloads.hindawi.com/journals/jchem/2020/1241952.pdf

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