Electromagnetic Properties of Inner Double Walled Carbon Nanotubes Investigated by Nuclear Magnetic Resonance

Author:

Bouhrara M.1ORCID,Abou-Hamad E.23ORCID,Alabedi G.1,Al-Taie I.1,Kim Y.4,Wågberg T.5,Goze-Bac C.2

Affiliation:

1. Design Nano Applications Division (DNA), Research & Development Center, Saudi Aramco, Dhahran 31311, Saudi Arabia

2. nanoNMRI group, UMR5587, University of Montpellier II, 34095 Montpellier, France

3. KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia

4. Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, PA19104, USA

5. Department of Physics, Umeå University, 901 87 Umeå, Sweden

Abstract

The nuclear magnetic resonance (NMR) analytical technique was used to investigate the double walled carbon nanotubes (DWNTs) electromagnetic properties of inner walls. The local magnetic and electronic properties of inner nanotubes in DWNTs were analyzed using 25%13C enriched C60by which the effect of dipolar coupling could be minimized. The diamagnetic shielding was determined due to the ring currents on outer nanotubes in DWNTs. The NMR chemical shift anisotropy (CSA) spectra and spin-lattice relaxation studies reveal the metallic properties of the inner nanotubes with a signature of the spin-gap opening below 70 K.

Publisher

Hindawi Limited

Subject

General Materials Science

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