Complexes With Biologically Active Ligands. Part 71 Synthesis and Fungitoxic Activity of Metal Complexes Containing 1,3,5-tris-(8-Hydroxyquinolino)- Trichlorocyclo-Triphosphazatriene

Author:

Barboiu Mihai1,Guran Cornelia2,Jitaru Ioana2,Cimpoesu Marilena3,Supuran Claudiu T.4

Affiliation:

1. Research Center for Macromolecular Materials and Membranes, Splaiul Independentei 206, Bucharest 79611, Romania

2. Polytechnic University of Bucharest, Department of Inorganic Chemistry, Polizu Str. 1, Bucharest 79611, Romania

3. University of Bucharest, Department of Inorganic Chemistry, Str. Dumbrava Rosie 23, Bucharest, Romania

4. Università degli Studi, Dipartimento di Chimica, Laboratorio di Chimica Inorganica e Bioinorganica, Via Gino Capponi 7, Florence I-50121, Italy

Abstract

Complexes containing 1,3,5-tris-(8-hydroxyquinolino)-trichlorocyclotriphosphazatriene, a new cyclophosphazene ligand, and Co(II), Cu(II) and Ni(II) were prepared. The new complexes, having the general formula [MLCl2], [ML2]Cl2, (M=Cu, Co, Ni); [NiLAc], [NiL2Ac]Ac and [ML3]X3 (M=Ni, Co, X=Cl, Ac) were characterised by elemental analysis, electronic-, IR spectroscopy, and electrical conductivity measurements. Some of them inhibited the growth of several fungi species (Aspergillus and Candida spp.)

Publisher

Hindawi Limited

Subject

Inorganic Chemistry,Drug Discovery,Pharmacology,Toxicology

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