Kinetic Study of the Adsorption of Polyphenols from Olive Mill Wastewater onto Natural Clay: Ghassoul

Author:

Allaoui Safae1ORCID,Naciri Bennani Mohammed1,Ziyat Hamid1ORCID,Qabaqous Omar1,Tijani Najib2,Ittobane Najim3

Affiliation:

1. Laboratory of Chemistry-Biology Applied to the Environment, Research Team “Applied Materials and Catalysis”, Chemistry Department, Faculty of Sciences, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, Morocco

2. Research Team “Membrane Materials and Separation Processes, Chemistry Department, Faculty of Science, Moulay-Ismaïl University, BP. 11201-Zitoune, Meknes 50000, Morocco

3. Research Team “Biomolecular and Macromolecular Chemistry, Chemistry Department, Faculty of Science, Moulay-Ismaíl University, BP. 11201-Zitoune, Meknes 50000, Morocco

Abstract

The aim of this study is based on natural clay as an adsorbent in the elimination of polyphenols from olive mill wastewater (OMW). This clay was analyzed using XRD, SEM/EDX, FTIR, surface area measurement (BET method), thermal analysis (TGA/DTA), and X-ray fluorescence (XRF) and then used in adsorption experiments. The results reveal that the best quantity of adsorption of polyphenols is 161 mg/g at the temperature of 25°C, but they decrease at 35°C and 45°C. A great agreement with pseudo-second-order and Freundlich model is represented by kinetic and isotherms models, and several parameters such as ΔG0, ΔS0, and ΔH0 were determined using the thermodynamic function relationship.

Funder

MENFPESRS

Publisher

Hindawi Limited

Subject

General Chemistry

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