Distributions and Sources of Sedimentary Sterols as well as Their Indications of Sewage Contamination in the Guanting Reservoir, Beijing

Abstract

In this study, domestic sewage contamination in the Guanting Reservoir, one of the major water source reservoirs of Beijing, was examined using sterols as tracing molecular markers. Nineteen sediment samples in seven cross-sections in the Guanting Reservoir were collected, extracted, and analyzed by gas chromatography-mass spectrometry (GC-MS). Seven different sterols were identified and quantified from the surface sediment samples in the Guanting Reservoir. The total sterols in sediments of the reservoir ranged from 2.78 μg g−1 to 40.31 μg g−1 with the average concentration of 13.53 μg g−1. Concentrations of fecal sterols, coprostanol and epicoprostanol in the Guishui River reservoir area were generally higher than in the Yongding River reservoir area. The average concentrations of coprostanol and epicoprostanol in the Yongding River reservoir area were 0.41 μg g−1 and 0.34 μg g−1, respectively. The average concentrations of coprostanol and epicoprostanol in the Guishui River reservoir area were 0.72 μg g−1 and 0.70 μg g−1, respectively. Ratios of sterols indicated higher sewage pollution in regions close to river mouths and reservoir banks. Principal component analysis (PCA) indicated three distinct sources of sterols from domestic sewage, phytoplankton, and terrestrial higher plants. This article identified the current situation of sewage contamination in sediments of the Guanting Reservoir, which could provide important references for further implementation of pollution control and basin management in the region.