“Single Shot” Laser Multiphoton Ionization Detection of UF5 Following the 266 nm Photodissociation of UF6

Author:

Chou J. S.1,Sumida D.1,Stuke M.12,Wittig C.1

Affiliation:

1. University of Southern California, SSC 404, Mail Stop 0483, Los Angeles 90089, California, USA

2. Max-Planck-Institut fur biophysikalische Chemie, Postfach 968, Gottingen 3400, Germany

Abstract

By using laser multiphoton ionization and a time-of-flight mass filter, we have detected nascent UF5 from the 266 nm laser photodissociation of UF6, following a single laser firing. The method can be used to monitor these species under conditions wherein isotopically selective excitation is responsible for the dissociation of UF6.

Publisher

Hindawi Limited

Subject

Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Multiphoton Ionization of Gaseous Molecules;Advances in Chemical Physics;2007-03-14

2. Measurements of235U/238U isotopic ratio in the photoproduct UF5 by multiphoton ionization and time-of-flight mass spectrometry;Applied Physics B Laser and Optics;1996-05

3. An Apparatus for Isotopic Ratio Measurement in UF5Formed by Infrared Multiphoton Dissociation of UF6in Molecular Beam;Journal of Nuclear Science and Technology;1995-11

4. Multiphoton ionization of uranium hexafluoride;The Journal of Chemical Physics;1994-01

5. References;Laser Photoionization Spectroscopy;1987

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