Modification of Silica Rice Husk Ash to Solid Ammonium Sulphate for Second Generation Biofuels Productions

Author:

Hello Kasim Mohammed1,Mohammed Majid Jari2,Yasser Asstabraq Mohsen2,Adam Farook3ORCID,Farag Zinab3

Affiliation:

1. Chemistry Department, College of Science, Al-Muthanna University, Iraq

2. Chemistry Department, College of Science, Kufa University, Iraq

3. School of Chemical Sciences, University Sains Malaysia, 11800 Penang, Malaysia

Abstract

A new approach has been demonstrated for the synthesis of solid ammonium sulphate attached to silica rice husk ash. The 3-(aminopropyl)triethoxysilane was immobilized onto silica at room temperature to functionalize the silica with ammine end groups (–NH2). The amine group was sulphated with sulphuric acid to produce a novel micro-rod-like shaped acidic catalyst (as seen with TEM) designated RHNH3SO4H (RH = rice husk). The TGA analysis shows that the catalyst is stable at temperatures below 200°C. The acidity measurement of the catalyst indicates that it has Brønsted acid sites. Cellulose extracted from waste of rice husk and cellulose extracted from office paper were hydrolysed to glucose in 6 h, and the glucose was hydrolysed afterwards to other products within 13 h. The catalyst is reusable many times without a significant loss of catalytic activity.

Publisher

Hindawi Limited

Subject

General Medicine

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Effect of Different Acids on Rice Husk Calcination and Extraction of Bio-Silica;Asian Journal of Chemistry;2022

2. Cellulose hydrolysis over sodium hydrogen sulfate;PROCEEDING OF THE 1ST INTERNATIONAL CONFERENCE ON ADVANCED RESEARCH IN PURE AND APPLIED SCIENCE (ICARPAS2021): Third Annual Conference of Al-Muthanna University/College of Science;2022

3. Solid Urea Sulfate Catalyst for Hydrolysis of Cellulose;Waste and Biomass Valorization;2016-09-20

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