Electrophoretic Codeposition of MoOx/MoS2 Thin Film for Platinum-Free Counter Electrode in Quantum Dot Solar Cells

Author:

Nguyen Thanh Tung1ORCID,Ngo Huy Phap23,Le Van Thang24,Huynh Le Thanh Nguyen23ORCID,Le Viet Hai23,Nguyen Thai Hoang23ORCID,Ngo Hoang Long1ORCID

Affiliation:

1. NTT Hi-Tech Institute, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, 700000 Ho Chi Minh City, Vietnam

2. Vietnam National University, Linh Trung Ward, Thu Duc City, 700000 Ho Chi Minh Chi City, Vietnam

3. University of Science, 227 Nguyen Van Cu, District 5, 700000 Ho Chi Minh City, Vietnam

4. Faculty of Materials Technology, Bach Khoa University, 268 Ly Thuong Kiet, District 10, 700000 Ho Chi Minh City, Vietnam

Abstract

The MoOx/MoS2 thin films were manufactured on conducting glass (FTO) from the ethanolic mixture of colloidal molybdenum disulfide (MoS2) and molybdenum oxides (MoOx) by electrophoretic deposition method and were used for counter electrode of quantum dot solar cells. Different ramp-rate conditions for electrophoretic deposition as well as bias potential were investigated in an attempt to get the highest possible electrocatalytic activity of polysulfide (S2-/Sn2-) redox couple. In this research, interestingly, by simply using CdS/CdSe/ZnS photoanode and polysulfide electrolyte under 1000 W.m−2 AM 1.5 G illumination, the power conversion efficiency of MoOx/MoS2-counter-electrode-based QDSC was achieved up to 2.01%, which was double compared to platinum-based counter electrode of QDSCs.

Publisher

Hindawi Limited

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,Atomic and Molecular Physics, and Optics,General Chemistry

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