Synthesis and Characterization of Acrylic Acid-g-(-Carrageenan) Copolymer and Study of Its Application

Author:

Srivastava Arti1ORCID,Kumar Rajesh2ORCID

Affiliation:

1. Department of Chemistry, School of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh 495009, India

2. Organic Polymer Laboratory, Department of Chemistry, Centre of Advanced Studies in Chemistry, Banaras Hindu University, Varanasi, Uttar Pradesh 221 005, India

Abstract

The effects of concentrations of peroxymonosulphate, mercaptosuccinic acid, hydrogen ion, acrylic acid, and carrageenan on grafting parameters were studied to find out the maximum grafting ratio. The corresponding values were found to be , , ,  mol dm−3, and  g dm−3, respectively. The optimal reaction time duration and reaction temperature were found to be 120 min and 40°C, respectively. The effect of hydrogen ion variation from 5.0 up to  mol dm−3 shows prompt changes on grafting parameter. The grafted copolymer was found more thermally stable than the ungrafted substrate. Also the grafted copolymer absorbed more water, namely hazardous metal cations. Hg2+, Pb2+, and Cd2+, showed better flocculation behavior than carrageenan.

Publisher

Hindawi Limited

Subject

General Earth and Planetary Sciences,General Environmental Science

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