Doping ofTiO2Polymorphs for Altered Optical and Photocatalytic Properties

Author:

Nie Xiliang12,Zhuo Shuping13,Maeng Gloria1,Sohlberg Karl1

Affiliation:

1. Department of Chemistry, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104, USA

2. Hampton University Proton Therapy Institute, Hampton, VA, USA

3. School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China

Abstract

This paper reviews recent investigations of the influence of dopants on the optical properties ofTiO2polymorphs. The common undoped polymorphs ofTiO2are discussed and compared. The results of recent doping efforts are tabulated, and discussed in the context of doping by elements of the same chemical group. Dopant effects on the band gap and photocatalytic activity are interpreted with reference to a simple qualitative picture of theTiO2electronic structure, which is supported with first-principles calculations.

Funder

U.S. Department of Energy

Publisher

Hindawi Limited

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,Atomic and Molecular Physics, and Optics,General Chemistry

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