Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime-Reference-Cited by-同舟云学术

Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime

Published:2010 Issue: Volume:2010 Page:1-9
ISSN:1565-3633
Container-title:Bioinorganic Chemistry and Applications
language:en
Short-container-title:Bioinorganic Chemistry and Applications

Author:

Efthymiou Constantinos G.¹²,Nastopoulos Vassilios¹^ORCID,Raptopoulou Catherine³,Tasiopoulos Anastasios⁴,Perlepes Spyros P.¹^ORCID,Papatriantafyllopoulou Constantina²^ORCID

Affiliation:

1. Department of Chemistry, University of Patras, 265 04 Patras, Greece

2. Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA

3. Institute of Materials Science, National Centre of Scientific Research “Demokritos”, 153 10 Aghia Paraskevi Attikis, Greece

4. Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus

Abstract

The reactions of methyl(2-pyridyl)ketone oxime, (py)C(Me)NOH, with manganese(II) sulfate monohydrate have been investigated. The reaction between equimolar quantities ofMnSO4⋅H2Oand (py)C(Me)NOH inH2Olead to the dinuclear complex[Mn2(SO4)2{(py)C(Me)NOH}4]⋅(py)C(Me)NOH,1⋅(py)C(Me)NOH, while employment of NaOMe as base affords the compound[Mn(HCO2)2{(py)C(Me)NOH}2](2). The structures of both compounds have been determined by single crystal X-ray diffraction. In both complexes, the organic ligand chelates through its nitrogen atoms. The IR data are discussed in terms of the nature of bonding and the structures of the two complexes.

Publisher

Hindawi Limited

Subject

Inorganic Chemistry,Organic Chemistry,Biochemistry

Link

http://downloads.hindawi.com/journals/bca/2010/960571.pdf

Reference40 articles.

1. The coordination chemistry of pyridyl oximes

2. Structural and Spectroscopic Studies of the Versatile Coordination Chemistry of the Chiral Ligand N,N-Bis(1-propan-2-onyl oxime)-l-methionine N‘-Methylamide with NiII and ZnII

3. X-ray spectroscopy of the photosynthetic oxygen-evolving complex

4. Heteronuclear Mn–Ca/Sr complexes, and Ca/Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex of Photosystem II

5. Encapsulation by a Chromium(III)-Containing Bicyclic Ligand Cage. Synthesis, Structures, and Physical Properties of Heterometal Complexes CrIIIMCrIII [M = (H+)2, Li(I), Mg(II), Cu(II), Ni(II), Ni(IV), Co(III), Fe(II), Fe(III), Mn(II)]

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