Affiliation:
1. Department of Chemistry and Biochemistry, School of Medicine, University of Zagreb, 10000 Zagreb, Croatia
Abstract
Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate (II) complex have been characterized by means of UV/Vis, Raman, and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate (II), [Fe(CN)5(H2O)]3−, in buffered aqueous solutions yielded the [Fe(CN)5(MMI)]3−complex. It was found that only thione tautomer of MMI coordinates to the iron (II). The exceptionally stabile and inert complex was produced.
Cited by
4 articles.
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1. FORMULATION, DEVELOPMENT AND EVALUATION OF SUSTAINED RELEASE MATRIX TABLET OF METHIMAZOLE;INDO AM J PHARM SCI;2018
2. Metal(II) Ion Complexes with 5-(Pyrazin-2-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione; Synthesis, Structural Characterization, Acid-base, and Complexing Properties in Solution;Zeitschrift für anorganische und allgemeine Chemie;2017-07-27
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