Adsorption of Chromium Ions from Aqueous Solutions by Synthesized Nanoparticles

Author:

Kandasamy Senthilkumar1ORCID,Velusamy Sampathkumar2ORCID,Thirumoorthy Pradeep2,Periyasamy Mageshkumar3ORCID,SenthilkumarVeerasamy 4,Gopalakrishnan K. M.5,Sathish U.6,Kiramani Vallarasu5,Antrini Fathima Darras Gracy5,Periyasamy Selvakumar7ORCID

Affiliation:

1. Department of Chemical Engineering, Kongu Engineering College, Erode 638060, India

2. Department of Civil Engineering, Kongu Engineering College, Erode 638060, India

3. Department of Civil Engineering, K.S. Rangasamy College of Technology, Thiruchengode, Namakkal 637215, India

4. Department of Civil Engineering, M. Kumarasamy College of Engineering, Karur 639113, India

5. Department of Civil Engineering, Erode Sengunthar Engineering College, Erode 638057, India

6. Department of Civil Engineering, VSB College of Engineering Technical Campus, Coimbatore 642109, India

7. Department of Chemical Engineering, School of Mechanical, Chemical and Materials Engineering, Adama Science and Technology University, Adama 1888, Ethiopia

Abstract

In the present manuscript, an attempt has been made to remove chromium metal ions from synthetic effluent using adsorption process. The synthesized titanium dioxide nanoparticles were used as adsorbents. Adsorption studies were performed in batch process. Various characterization of synthesized nanoparticles such as XRD analysis, optical properties of nanoparticles using UV-visible absorption spectroscopy, concentration of chemical bonds, and atomic arrangement using (FTIR) have been performed and analyzed. The dependency of adsorption percentage of metal ions and equilibrium amount of metal adsorbed with respect to pH, adsorbent dosage, initial concentration, and temperature are studied. Mechanisms of metal ion adsorption process explained by various adsorption isotherms and adsorption kinetic models. The criteria for statistical significance of correlation coefficient ( R 2 ) for fitting the experimental data to the various isotherms were tested and analyzed. The experimental results reveal that synthesized titanium dioxide nanoparticles could be used as adsorbents in order to remove chromium ions present in industrial wastewater.

Publisher

Hindawi Limited

Subject

General Materials Science

Reference26 articles.

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2. Adsorption studies on the removal of hexavalent chromium- contaminated wastewater using activated carbon and bentonite;W. Salah Abdel;Asian Journal of Chemistry,2012

3. Experimental Studies on Disposal of Various Industrial Solid Wastes

4. Co-precipitation method of synthesis and characterization of iron oxide nanoparticles;N. D. Kandpal;J. Sci. Ind. Res.(India),2014

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