Separation Process of Fine Coals by Ultrasonic Vibration Gas-Solid Fluidized Bed

Author:

Wang Shuai1ORCID,He Yaqun12ORCID,Wei Hua1,Xie Weining1

Affiliation:

1. Advanced Analysis and Computation Center, China University of Mining and Technology, Xuzhou 221116, China

2. School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Abstract

Ultrasonic vibration gas-solid fluidized bed was proposed and introduced to separate fine coals (0.5–0.125 mm fraction). Several technological methods such as XRF, XRD, XPS, and EPMA were used to study the composition of heavy products to evaluate the separation effect. Results show that the ultrasonic vibration force field strengthens the particle separation process based on density when the vibration frequency is 35 kHz and the fluidization number is 1.8. The ash difference between the light and heavy products and the recovery of combustible material obtain the maximum values of 47.30% and 89.59%, respectively. The sulfur content of the heavy product reaches the maximum value of 6.78%. Chemical state analysis of sulfur shows that organic sulfur (-C-S-), sulfate-sulfur (-SO4), and pyrite-sulfur (-S2) are confirmed in the original coal and heavy product. Organic sulfur (-C-S-) is mainly concentrated in the light product, and pyrite-sulfur (-S2) is significantly enriched in the heavy product. The element composition, phase composition, backscatter imagery, and surface distribution of elements for heavy product show concentration of high-density minerals including pyrite, quartz, and kaolinite. Some harmful elements such as F, Pb, and As are also concentrated in the heavy product.

Funder

National Natural Science Foundation of China

Publisher

Hindawi Limited

Subject

Analytical Chemistry

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