A Novel Baker’s Yeast-Mediated Microwave-Induced Reduction of Racemic 3-Keto-2-Azetidinones: Facile Entry to Optically Active Hydroxy β-Lactam Derivatives-Reference-Cited by-同舟云学术

A Novel Baker’s Yeast-Mediated Microwave-Induced Reduction of Racemic 3-Keto-2-Azetidinones: Facile Entry to Optically Active Hydroxy β-Lactam Derivatives

Published:2022-06 Issue:2 Volume:9 Page:195-198
ISSN:2213-3372
Container-title:Current Organocatalysis
language:en
Short-container-title:COCAT

Author:

Banik Bimal Krishna¹,Das Aparna²^ORCID,Yadav Ram Naresh³

Affiliation:

1. Department of Mathematics and Natural Sciences, College of Sciences and Human Studies, Deanship of Research, Prince Mohammad Bin Fahd University, Al Khobar 31952, Kingdom of Saudi Arabia

2. Department of Mathematics and Natural Sciences, College of Sciences and Human Studies, Prince Mohammad Bin Fahd University, Al Khobar 31952, Kingdom of Saudi Arabia

3. Department of Chemistry, Faculty of Engineering & Technology, Veer Bahadur Singh Purvanchal University, Jaunpur Uttar Pradesh, India

Abstract

Objective: Microwave technology, together with enzymatic catalysis, is a nature-friendly chemical synthesis method with low wastage of solvent and a good yield of the products. Methods: Enzymes from various microorganisms can be used in the biochemical processes of a wide range of compounds assisted by microwave irradiation. Results: In this work, the microwave-induced reaction of α-keto β-lactams by Baker's yeast in organic solvent was conducted to afford optically active cis and trans-α-hydroxy-β-lactams for the first time. Conclusion: These hydroxy compounds are the precursors of numerous natural products of medicinal significance.

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Analytical Chemistry,Catalysis

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