An Efficient One-pot Stereoselective Synthesis of 2,6-disubstituted 4-thiocyanatotetrahydropyrans-Reference-Cited by-同舟云学术

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An Efficient One-pot Stereoselective Synthesis of 2,6-disubstituted 4-thiocyanatotetrahydropyrans

Published:2021-12 Issue:3 Volume:8 Page:266-270
ISSN:2213-3372
Container-title:Current Organocatalysis
language:en
Short-container-title:COCAT

Author:

Sudhakar Chithaluri¹^ORCID,Ramudu Pochamoni²^ORCID

Affiliation:

1. Department of Chemistry, GITAM School of Science, GITAM Deemed to be University, Telangana-502 329, India

2. Department of Chemistry, PG center wanaparthy, Palamuru University, Telangana – 509001, India

Abstract

An efficient stereoselective synthesis of 2,6-disubstituted-4-thiocyanatotetrahydropyrans has been developed through a one-pot three-component reaction of aldehydes, trimethyl allylsilane, and NH4SCN in the presence of BF3.Et2O at room temperature. The products are formed rapidly (10-30 min) in excellent yields (78-98%).

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Analytical Chemistry,Catalysis

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