Author:
Wang Tianhui,Li Haitao,Wang Junchao,Jia Yunlin,Liu Lifeng
Abstract
A novel dinuclear Cu(II) complex material has been synthesized by the reaction of 1, 2-phenylenedioxydiacetic
acid, 1,10-phenantroline (phen) and Cu(CHCOO)·HO. And it has been characterized by elemental analysis, IR, UV and
single crystal X-ray diffraction. The crystal belongs to tetragonal, space group I4/ with = = 25.381(4) Å, = 32.044(6) Å, = 20643(6) Å, = 16, D= 1.395 g·cm, = 0.898 mm, (000) = 8896, and final = 0.1026, = 0.3142. The structural analysis shows that two Cu(II) atoms adopt different coordination modes, Cu has five-coordination
with a trigonal bipyramidal configuration, and Cu has four-coordination with a distorted square planar configuration. The
cyclic voltammetric behaviour of the dinuclear Cu(II) complex has been investigated.
Publisher
Bentham Science Publishers Ltd.
Cited by
3 articles.
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