High Surface Area Mesoporous Silica for Hydrogen Sulfide Effective Removal

Author:

Mohammed Ali Gomaa Abdelgawad1,Barhoum Ahmed2,Gupta Vinod Kumar3,Nada Amr Ahmed4,El-Maghrabi Heba Hassan4,Kanthasamy Ramesh5,Shaaban Essam Ramadan6,Algarni Hamed7,Chong Kwok Feng8

Affiliation:

1. Chemistry Department, Faculty of Science, Al-Azhar University, Assiut, 71524, Egypt

2. Chemistry Department, Faculty of Science, Helwan University, Helwan, Cairo 11795, Egypt

3. Center of Excellence for Advanced Materials Research, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia

4. Institut Europeen des Membranes, Universite Montpellier 2, CC 047, Place Eugene Bataillon, 34095, Montpellier Cedex 5, France

5. Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Gambang, 26300, Kuantan, Malaysia

6. Physics Department, Faculty of Science, Al-Azhar University, Assiut, 71524, Egypt

7. Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, P. O. Box 9004, Saudi Arabia

8. Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, Gambang, 26300 Kuantan, Malaysia

Abstract

Background: Removal of sulfur-containing compounds from the aqueous environment is necessary as these compounds pose potential risks to human health, hygienic management and bring great economic losses due to fouling of resin bed and corrosion of process equipment. Objective: This work aims to study the H2S removal efficiency using high surface area mesoporous silica (MCM–41). Methods: In this study, mesoporous silica (MCM–41) with a high surface area of 1270 m2/g and high porosity of 69% was prepared by sol-gel technique. Results: The obtained MCM–41 has exhibited a superior performance in adsorbing H2S from wastewater with a maximum adsorption capacity of 52.14 mg/g. The adsorption isotherm and kinetics of the current adsorption process are best represented by Freundlich isotherm and pseudo-secondorder models, respectively. Conclusion: Therefore, MCM–41 is an excellent adsorbent for wastewater treatment applications.

Funder

Ministry of Education Malaysia FRGS

Universiti Malaysia Pahang

King Khalid University

Publisher

Bentham Science Publishers Ltd.

Subject

Pharmaceutical Science,Biomedical Engineering,Medicine (miscellaneous),Bioengineering,Biotechnology

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