Friedel-Crafts Benzylation of Unprotected Anilines with Indole-3-carbinols to Access Trifluoro-methyl(indolyl)phenylmethanes-Reference-Cited by-同舟云学术

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Friedel-Crafts Benzylation of Unprotected Anilines with Indole-3-carbinols to Access Trifluoro-methyl(indolyl)phenylmethanes

Published:2021-02-25 Issue: Volume:18 Page:
ISSN:1570-1786
Container-title:Letters in Organic Chemistry
language:en
Short-container-title:LOC

Author:

Chigumbu Paidamoyo¹,Fu Junfeng¹,Takia Ingrid Rakielle Tsapy¹,Wang Yongjiang¹,Han Xiaoyu¹^ORCID

Affiliation:

1. Provincial Key Laboratory for Chemical & Biological Processing, Technology of Farm Products, School of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou, Zhejiang, China

Abstract

: An unprecedented protocol for the efficient and highly chemoselective alkylation of unprotected anilines with deactivated CF3-indole-3-carbinols promoted by In(OTf)3 has been developed. A series of diversified trifluoromethylated (indolyl)phenylmethanes were produced featuring the C-alkylation in moderate to high chemical yields and with high regioselectivities.

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Biochemistry

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