Recent Advances in Organic Synthesis Using Glycerol as a Green Media-Reference-Cited by-同舟云学术

Recent Advances in Organic Synthesis Using Glycerol as a Green Media

Published:2023-10 Issue:10 Volume:20 Page:945-957
ISSN:1570-1786
Container-title:Letters in Organic Chemistry
language:en
Short-container-title:LOC

Author:

Narasimhamurthy Kereyagalahally H.¹,Joy Muthipeedika Nibin²,Sajith Ayyiliath M.³,Santra Sougata²,Zyryanov Grigory V.²⁴,Swaroop Toreshettahally R.¹,Rangappa Kanchugarakoppal S.⁵

Affiliation:

1. Department of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysuru, 570006, Karnataka India

2. Institute of Chemical Technology, Ural Federal University, 19 Mira Street, Yekaterinburg, 620002, Russia

3. School of Chemical Sciences, Kannur University, Payyanur Campus, Kannur, 670327, Kerala, India

4. I. Ya. Postovskiy Institute of Organic Synthesis, Ural Division of the Russian Academy of Sciences, 22 S. Kovalevskoy Street, Yekaterinburg, 620219, Russia

5. Vignana Bhavana, University of Mysore, Manasagangotri, Mysuru, 570006, Karnataka, India

Abstract

Abstract: Various catalytic and non-catalytic organic transformations are carried out in glycerol media with superior efficiency over commonly employed organic solvents. The success of glycerol as a green media is due to its exceptional H-bonding properties, which result in enhanced reactivity in many organic transformations. In addition, its highly polar nature and non-toxic properties, recyclability, large availability as an organic waste from the biodiesel industry, high boiling point, low vapor pressure and low price further extend the scope of this solvent as green media. In this review, we present the potential use of glycerol as a green solvent in many organic transformations in two sections: cyclization reactions and miscellaneous reactions.

Funder

Grants Council of the President of the Russian Federation

Russian Science Foundation

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Biochemistry

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