Affiliation:
1. Department of Chemistry, Indian Institute of Engineering Science and Technology, Shibpur, Botanic Garden, Howrah 711103, India
2. Department of Chemistry, Government General Degree College Mangalkote (Affiliated to the University of Burdwan), Khudrun,
Purba Bardhaman 713143, India
3. Sovarani Memorial College, Jagatballavpur, Howrah 711408, WB, India
Abstract
ABSTRACT:
The last decade has witnessed a remarkable progress in the field of nanoscience and
nanotechnology. Nanoparticles have been extensively used in diverse areas, including medicine,
sensor, and catalysis. The easy accessibility of nanoparticles (NPs) with different shapes,
sizes and compositions has inspired researchers to investigate their applications in catalysis.
Recently, magnetic nanoparticles, such as iron-based nanoparticles, have attracted much consideration
due to their unique properties, such as superparamagnetism, greater surface area,
surface-to-volume ratio, and easy separation methodology. They increase the competence of
organic reactions in terms of activity, selectivity, yield, simplicity, and sustainability. In this
review, we focus on the developments of iron/iron oxide-based nanoparticles-catalyzed organic
reactions and some examples of magnetic iron oxide nanoparticles as carriers/support for the
main catalyst in organic reactions. Owing to magnetic properties, these nanocatalysts can be easily recovered from
the reaction mixture by an external magnet and reused for several runs without loss of catalytic activity. Iron-based
nanoparticles are used in a wide range of catalytic processes and applications. Notable focus has been on the hydrogenation
of alkenes and alkynes, and also the hydrogenation of nitroarenes to aniline. Other catalyzed organic reactions,
such as hydroboration of aldehydes and ketones, oxidative dehydrogenation of N-heterocycles, azide-alkyne
cycloaddition reactions, synthesis of various heterocyclic compounds, multicomponent reactions, and crosscoupling
reactions for C–C and C–heteroatom bond formation have been covered.
Funder
SERB, DST, Government of India
WBDST-BT via government
Publisher
Bentham Science Publishers Ltd.
Cited by
20 articles.
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1. Methyl orange sorption on octadecylamine-modified iron oxide magnetic nanoparticles;Chimica Techno Acta;2024-07-22
2. Preface;ACS Symposium Series;2024-05-14
3. Editors’ Biographies;ACS Symposium Series;2024-05-14
4. Subject Index;ACS Symposium Series;2024-05-14
5. Title, Copyright, Foreword;ACS Symposium Series;2024-05-14