Fundamental thermodynamics of fuel cell, engine, and combined heat and power system efficiencies

Abstract

At the 2001 Grove Symposium on Fuel Cells attended by representatives of the world-wide fuel cell industry, fuel cells and fuel cells integrated with gas turbines were discussed. Combined heat and power (CHP) aspects were also discussed. Without exception, efficiency figures were irrationally based on the measured, Carnot-limited, lower calorific value (CV) of the fuel in energy units J. The rational basis, on the other hand, is the fuel chemical exergy (work units, Ws) calculated via an equilibrium diagram. In Joules experiment 1 Ws ≫ 1 J, where the irreversible ≫ must not become an = sign. A misnomer like potential energy (exergy) fits on the left of the diagram, CV on the right. Moreover credence was also given, at the symposium, to the popular misconception that a CHP system has an efficiency of the order of 80 per cent. An essential precursor to reading the paper is to grasp the theory of chemical equilibrium and equilibrium constants [3] as an aid to exploring the equilibrium diagram mentioned above.