Zinc(II) and Cadmium(II) Salphen Catalyzed Alkylation Reactions to Form α-Alkylated Ketones

Author:

GÜNNAZ Salih1

Affiliation:

1. EGE UNIVERSITY, FACULTY OF SCIENCE

Abstract

The zinc (II) and cadmium (II)-salphen catalyzed α-alkylation of ketones with primary alcohols is reported. Various α-alkylated ketones were obtained in good yields through a borrowing hydrogen strategy by using 1 % of catalysts and a catalytic amount of NaOH (10 mol%) as the base under air atmosphere. All synthesized compounds were characteized by 1H and 13C NMR.

Publisher

Erzincan Universitesi Fen Bilimleri Ensitusu Dergisi

Subject

Microbiology

Reference16 articles.

1. [1] (a) Narges, K., Abdolreza, R., Maasoumeh J. (2020). Silica Iminopyridine-Functionalized Nanomaghemite Enhances the Oxygenation Activity and Durability of Simple Co (II) Salophen Complex. Appl. Organomet. Chem., 34, e5535. (b) Hongyue, L., Dandan, X., Yan, N., Chao, W., Fengrong, X., Lei, L., Ping, X. (2019). Design, Synthesis and Biological Evaluation of Cobalt (II)-Schiff Base Complexes As ATP-Noncompetitive MEK1 Inhibitors. J. Inorg. Biochem., 195, 174-181.

2. [2] Asraf, M. A., Ezugwu, C. I., Zakaria, C. M., Verpoort, F. (2019). Homogeneous Photochemical Water Oxidation with Metal Salophen Complexes in Neutral Media. Photochem. Photobiol. Sci., 18, 2782-2791.

3. [3] Mehta, J. P., Parmar, D. K., Godhani, D. R., Nakum, H. D., Desai, N. C. (2016) Heterogeneous Catalysts Hold the Edge Over Homogeneous Systems: Zeolite-Y Encapsulated Complexes for Baeyer-Villiger Oxidation of Cyclohexanone. J. Mol. Catal. A-Chem., 421, 178-188.

4. [4] (a) Yankin, A. N., Lukyanov, D. A., Beletskii, E. V., Bakulina, O. Y., Vlasov, P. S., Levin, O. V. (2019). Aryl‐Aryl Coupling of Salicylic Aldehydes through Oxidative CH‐activation in Nickel Salen Derivatives. ChemistrySelect, 4, 8886-8890. (b) Choudhary, A., Das, B., Ray, S. (2016). Enhanced Catalytic Activity and Magnetization of Encapsulated Nickel Schiff-Base Complexes in Zeolite-Y: A Correlation with The Adopted Non-Planar Geometry. Dalton Trans., 45, 18967-18976.

5. [5] Toniolo, D., Scopelliti, R., Zivkovic, I., Mazzanti, M. (2020). Assembly of High-Spin [Fe3] Clusters by Ligand-Based Multielectron Reduction. ‎J. Am. Chem. Soc., 142, 7301-7305.

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