Assessment of strontium transport in clay medium by using a reactive transport modelling approach – an HP1 case study model

Author:

Antonov Dimitar1ORCID

Affiliation:

1. Geological Institute, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 24, 1113 Sofia, Bulgaria

Abstract

Modelling of radionuclide transport in the geosphere is a key issue of the evaluation of safety of low- and intermediate-level radioactive waste (LILW) repositories. In Bulgaria, due to the operation of Kozloduy Nuclear Power Plant (NPP), a building of such facility is ongoing. The migration of 90Sr was evaluated by simulation of flow and chemical modelling, performed with coupled numerical code HP1. The adsorption properties of the clays were implemented in the code by surface complexation reactions between strontium and iron oxides. The results were compared with another model performed with computer code HYDRUS 1-D, in which the adsorption properties of the medium were evaluated with the relevant for strontium distribution coefficient, Kd.

Publisher

Geological Institute, Bulgarian Academy of Sciences

Subject

General Earth and Planetary Sciences

Reference14 articles.

1. Antonov, D., Mallants, D. 2008. Determination of soil hydraulic properties of potential low and intermediate level waste disposal sites in Bulgaria. Assistance to site selection and site evaluation for low and intermediate level waste disposal in Bulgaria. External Report, CO-90-99-1220-05, Studiecentrum voor Kernenergie/Centre d’Étude de l’énergie Nucléaire, 41 pp.

2. Antonov, D., Karastanev, D., Mallants, D. 2012. Determination of soil hydrological parameters of a multi-layered loess complex using HYDRUS-2D and field infiltration experiments. Compte rendus de l’Académie bulgare des Sciences 65 (12), 1717–1724.

3. Appelo, C.A.J., Postma, D. 2007. Geochemistry, groundwater and pollution (Second Edition). Balkema Publishers, Leiden, Netherlands, 649 pp.

4. Dzombak, D.A., Morel, F.M.M. 1990. Surface complexation modeling: Hydrous ferric oxide. John Wiley & Sons, New York, 393 pp.

5. Environmental Protection Agency. 1999a. Understanding variation in partition coefficient, Kd, values (I), EPA 402-R99-004A, 212 pp.

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