Physicochemical modification of heat-shrinkable epoxy polymers

Abstract

An approach to the physicochemical modification of heat-shrinkable epoxy-diane polymers was considered, these polymers being used as couplings for the repair of polymer pipelines for various functional purposes. The purpose of the modification is to stabilize and improve the performance of the end couplings that are heat-shrinkable. We assessed the prospects of preparation of the products of various profiles by forming cross-linked polymers in a highly elastic state by plunger extrusion via creating favorable conditions for the orientation of interstitial fragments in epoxy-diane polymers. The starting epoxy-diane composition contained rigid and elastic components. The polymers fabricated by hardening of these compositions have both a glass transition temperature, which is convenient for operation, and high deformability in glassy and highly elastic states. We investigated the tensile strength, the elastic modulus, the failure deformation and the flaring deformation of the inner diameter of the preform of epoxy-diane polymers. Physical modification of a liquid filled epoxy-diane composition before mixing with a hardener was performed by using low-frequency ultrasonic treatment. We analyzed the results associated with the effect of combined ultrasonic treatment on the physical-mechanical and service properties of heat-shrinkable epoxy-diane polymers filled with short glass fibers.