A Simple Model for Predicting Heat Aging of EPDM Rubber

Abstract

Abstract Heat aging stability is a hallmark of EPDM rubber and a requirement for use in automotive, roofing and other applications. Retention of physical properties after accelerated heat aging is a typical specification for such long-term uses. This paper examines the utility of such tests in predicting results over a range of temperatures, 116 °C, 125 °C, 135 °C and 150 °C, in some cases for as long as 365 days. A simple empirical model was developed to predict the retention of physical properties using fractional strain energy, that is, the ratio of the aged to unaged products of tensile strength and elongation at break. Characteristic rates, an Arrhenius rate relationship and activation energies were determined. This model provides a basis to predict physical property changes over a wide range of temperatures and times, as well as for considerations of equivalent heat aging tests and use in different applications.