A MICROSCOPY INVESTIGATION OF RUBBER COMPOUND CRACK PRECURSORS AND TENSILE FRACTURE SURFACES

Abstract

ABSTRACT Tensile stress–strain testing is used to investigate the fracture behavior of carbon black–reinforced styrene–butadiene rubber, using 50 replicate specimens. Four vulcanized rubber compounds are studied: a CB-filled SBR with standard mixing conditions (control), the same formulation with intentional poor mixing of the CB, and materials identical to the control material but formed by adding minor amounts of 0.5-mm-diameter glass microspheres (beads)—serving as large model defects/inclusions—using a two-roll mill at two levels, corresponding to average values of 0.78 and 6.24 beads per gauge section region of the tensile test specimen. Microscopy analysis of the resulting fracture surfaces was conducted to complement our recent publication on Weibull failure statistics for distributions of tensile strength and crack precursor size. All 200 fractured specimens from tensile testing at 23°C were imaged with light microscopy and exhibited fracture surfaces characterized by relatively smooth planes perpendicular to the uniaxial loading direction. Most tensile failures originated from the edges of the dumbbell specimens, in line with expectations from fracture mechanics. Light microscopy revealed concentric fracture ring features of high specular reflectance emanating from crack precursors, which are a universal feature of the failure process for these compounds and independent of precursor type, size, or location. Noncontact interferometric microscopy confirmed that the rings resulted from variations in surface micro-roughness, proceeding outward from the precursor as rough–smooth–rough to the edge of the fracture surface. Fracture rings were also observed for tensile tests performed at 80°C. The variation in surface roughness of the fracture surface has parallels to the stick–slip tearing behavior seen for rubbers torn at medium to high rates. To the best of the authors’ knowledge, this is the first time that such striking features have been reported.