Cure and Mechanical Behavior of Rubber Compounds Containing Ground Vulcanizates: Part III. Tensile and Tear Strength

Author:

Gibala D.1,Thomas D.1,Hamed G. R.1

Affiliation:

1. 1Polymer Science Department, The University of Akron, Akron, OH 44325-3909

Abstract

Abstract A black-filled styrene-butadiene rubber (SBR) vulcanizate was ambiently ground, then used as an additive to the original, uncured compound. Sheets of the resulting composite (matrix/ground rubber particulate) were cured, and tensile and trouser tear strength determined. The composite had reduced tensile strength, but enhanced tear strength relative to the original vulcanizate. The contrasting behavior is attributed to the effects of sulfur migration into the particulate rubber and differences in the responses of a tensile and a tear testpiece to discontinuities. In brief, ground rubber acts as a stress-raising flaw in tensile testing, while promoting crack tip blunting and stick-slip behavior in trouser tearing.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

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