Rubber Chemicals Derived from Conjugate Addition. II. Synthesis of a Novel Class of Benzoquinone Diimines-Reference-Cited by-同舟云学术

Rubber Chemicals Derived from Conjugate Addition. II. Synthesis of a Novel Class of Benzoquinone Diimines

Published:2001-11-01 Issue:5 Volume:74 Page:927-945
ISSN:1943-4804
Container-title:Rubber Chemistry and Technology
language:en
Short-container-title:

Author:

Katritzky Alan R.¹,Odens Herman H.¹,Voronkov Michael V.¹,Rostek Charles J.²,Maender Otto W.²

Affiliation:

1. 1Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200 USA; e-mail katritzky@chem.ufl.edu

2. 2Flexsys America L. P., 260 Springside Drive, Akron Ohio, 44333 USA

Abstract

Abstract Various 2-alkylthio-5-amino- and 2,5-diamino-1,4-phenylenediamines were prepared by treatment of N-(1,3-dimethylbutyl)- N′-phenyl-1,4-quinonediimine with thiols and amines using air as an oxidizing agent. Key 2-alkylthio-1, 4-benzoquinone diimines were prepared via Ag2O oxidation of the corresponding 1,4-phenylenediamines.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

Link

http://meridian.allenpress.com/rct/article-pdf/74/5/927/1942481/1_3547662.pdf

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