Affiliation:
1. 1Monsanto Company, Rubber Chemicals Research Laboratories, Akron, Ohio 44313
Abstract
Abstract
The cure properties of thiocarbamyl amine disulfide (I) as vulcanizing agents are influenced by the ionic and steric nature of both R and R′. The relative effects of various R and R′ are analogous to those of R and R′ in thiuram disulfides and dithioamines, respectively. However, the cure properties of I are dominated by the type of R rather than R′. Among the types of R investigated relatively longer scorch delay, slower cure rate and lower crosslink density are obtained, when R is morpholino or 3-azabicyclo(3.2.2)non-3-yl.
Subject
Materials Chemistry,Polymers and Plastics
Cited by
7 articles.
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