CATIONIC COPOLYMERIZATION OF ISOBUTYLENE WITH ISOPRENE: KINETICS OF THE PROCESS AND DETERMINATION OF KINETIC CONSTANTS-Reference-Cited by-同舟云学术

CATIONIC COPOLYMERIZATION OF ISOBUTYLENE WITH ISOPRENE: KINETICS OF THE PROCESS AND DETERMINATION OF KINETIC CONSTANTS

Published:2015-12-01 Issue:4 Volume:88 Page:574-583
ISSN:0035-9475
Container-title:Rubber Chemistry and Technology
language:en
Short-container-title:

Author:

Ulitin N. V.¹,Tereshchenco K. A.¹,Shiyan D. A.¹,Zaikov G. E.²

Affiliation:

1. Department of Processing Technology of Polymers and Composite Materials, Kazan National Research Technological University, Kazan, 420015, Republic of Tatarstan, Russian Federation

2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119334, Russian Federation

Abstract

ABSTRACT A theoretical description has been developed of the kinetics of isobutylene with isoprene (IIR) cationic polymerization in the environment of methyl chloride on aluminum trichloride as the catalyst. Based on experimental data on the kinetics of copolymerization (isobutylene conversion curve) and the molecular weight characteristics of the copolymer of IIR, kinetic constants for the process were found. Adequacy of the developed theoretical description of the kinetics of the IIR copolymerization process was confirmed by comparing the experimental molecular-weight characteristics calculated by this description, independent characteristics, and IIR unsaturation.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

Link

http://meridian.allenpress.com/rct/article-pdf/88/4/574/1951675/rct_15_84889.pdf

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