CO2 SOLUBILITY AND DIFFUSIVITY AND RAPID GAS DECOMPRESSION RESISTANCE OF ELASTOMERS CONTAINING CNT

Abstract

ABSTRACT Understanding the structure–property relationship of elastomers is of critical importance in developing next-generation elastomers for high-pressure, high-temperature (HPHT) applications and in extending the application temperature and pressure range of existing oilfield products. Gas dissolution and diffusion in elastomers are essential to understanding the relationship among elastomer structures, rapid gas decompression (RGD) resistance, and sealing performance. Solubility and diffusivity (or diffusion efficiency) of carbon dioxide (CO2) in hydrogenated nitrile butadiene rubber (HNBR) and fluoroelastomers (FKM) comprising carbon nanotubes (CNT) were measured using a gravimetric method. The Rubotherm method was also used to estimate the solubility and swelling of HNBR in both subcritical liquid and supercritical CO2. It was demonstrated that CNT had a direct impact on CO2 solubility, diffusion, and mechanical properties of elastomers, hence improving the RGD resistance of the elastomers.