Mechanism of Smoke Inhibition by Hydrated Fillers

Abstract

Abstract The smoke inhibitory activity of hydrated fillers in SBR is centered primarily in condensed-phase processes and is analogous to the generally accepted mechanism of flame retardation by the hydrates. Dissipation of heat, which disfavors pyrolysis and favors competing crosslinking reactions is probably involved. These reactions should occur chiefly among polybutadiene segments of the polymers. In addition, the smoke-suppressant efficiency of hydrated fillers should depend upon the crosslinking efficiency of the rubber. Finally, although smoke generation in latex rubber goods presents a challenge, substantial practical reductions in visible smoke can be achieved through the selection of proper hydrated fillers.