The Preparation and Properties of meta-Carborane—Siloxane Elastomers-Reference-Cited by-同舟云学术

The Preparation and Properties of meta-Carborane—Siloxane Elastomers

Published:1975-03-01 Issue:1 Volume:48 Page:14-18
ISSN:1943-4804
Container-title:Rubber Chemistry and Technology
language:en
Short-container-title:

Author:

Peters E. N.¹,Hedaya E.¹,Kawakami J. H.¹,Kwiatkowski G. T.¹,McNeil D. W.¹,Tulis R. W.¹

Affiliation:

1. 1Union Carbide Corporation, Chemicals and Plastics, Bound Brook, New Jersey 08805, and Tarrytown Technical Center, Tarrytown, New York 10691

Abstract

Abstract A new synthesis of D2-carborane—siloxanes is described which overcomes many of the disadvantages of previous synthetic methods. Linear polymers with molecular weights up to 250,000 can now be prepared using silanol-silylurea condensation reactions. Elastomers with useful general properties and good retention of mechanical properties after heat aging in air at 315°C for 300 hr were produced. The property profile and ease of vulcanization suggest utility in high-performance sealant, gasket, O-ring, and coating applications.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

Link

http://meridian.allenpress.com/rct/article-pdf/48/1/14/1939417/1_3545034.pdf

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