INFRARED ANALYSIS OF FOULING DURING EPDM CURING STUDIED ON MOLDS MADE OF STEEL AND ALUMINIUM ALLOYS

Author:

Hanulikova Barbora1,Shejbalova Dana2,Dvorak Zdenek2

Affiliation:

1. Centre of Polymer Systems, Tomas Bata University in Zlin, 76001 Zlin, Czech Republic

2. Faculty of Technology, Tomas Bata University in Zlin, 76272 Zlin, Czech Republic

Abstract

ABSTRACT Mold fouling during the crosslinking process of EPDM rubber compounds results in defects in compression-molded products and deterioration of process conditions. Moreover, subsequent cleaning of molds is expensive and causes a loss at production. The fouling of several types of steel and aluminum alloys, which represent molds with variously machined surfaces, was analyzed during 0–70 cycles of EPDM molding. Fourier transform infrared microscopy was used for investigation of fouling and paraffin oil (softener) and/or EPDM fragments were detected in vibrational spectra of fouling as the most probable components of it. Metal specimens with a grinded surface were found to be more resistant to EPDM residue deposition.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

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