Influence of Silica and its Different Surface Treatments on the Vulcanization Process of Silica Filled SBR-Reference-Cited by-同舟云学术

Influence of Silica and its Different Surface Treatments on the Vulcanization Process of Silica Filled SBR

Published:2007-03-01 Issue:1 Volume:80 Page:183-193
ISSN:1943-4804
Container-title:Rubber Chemistry and Technology
language:en
Short-container-title:

Author:

Ramier J.¹,Chazeau L.¹,Gauthier C.¹,Guy L.²,Bouchereau M. N.²

Affiliation:

1. 1MATEIS (ex GEMPPM), UMR CNRS 5510, INSA de Lyon Bât. Blaise Pascal, 69621 Villeurbanne Cedex, France; email: laurent.chazeau@insa-lyon.fr

2. 2Rhodia Silice, 15 Rue Pierre Pays, B.P. 52, F-69660 Collonges au Mont d'Or

Abstract

Abstract The effect of different silica treatments on the vulcanization of silica filled Styrene Butadiene Rubber (SBR) is investigated. The concentration, the length and the functionality (coupling or non coupling) of the silane used for this treatment are the parameters studied. It is shown that the silane grafting, by covering the silica surface, modifies the adsorption and desorption on this surface of the accelerators used in the vulcanization system, which in turn modifies the crosslinking kinetic and therefore should influence the final crosslinking state of the matrix.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

Link

http://meridian.allenpress.com/rct/article-pdf/80/1/183/1945336/1_3548165.pdf

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