Preparation and photocatalytic performance of Sn-doped and BiOI-coupled dual modified Bi2WO6 composite

Abstract

Sn doped and BiOI coupled dual modified Bi2WO6 photocatalytic material was prepared using hydrothermal route. The phase composition, morphology, surface area, elemental composition and oxidation state, as well as optical properties, were comprehensively characterized. Take the methylene blue (MB) as the model pollutant for photodegradation to estimate the photocatalytic property of the synthesized material. The prepared Bi2WO6- based composite material shows a flower-like structure assembled from nanosheets, with a surface area of 45.3 m2 /g and a bandgap width of 2.41 eV, enabling visible light responsiveness. The synergistic effect of Sn doping and BiOI coupling modification enhances the photocatalytic performance. The Sn-BiOI/Bi2WO6 photocatalytic composite material shows excellent photocatalytic activity, with complete degradation of MB after 40 minutes of illumination, and a first-order reaction rate constant (k) of 0.102 min–1 . Experimental evidence suggests that photoinduced holes are the main active species.