Effect of ratio gold nanoparticles on the properties and efficiency photovoltaic of thin films of amorphous tungsten trioxide

Abstract

At a substrate temperature of 320 o C, a chemical spray pyrolysis approach was applied. to create tungsten oxide thin films on glass substrates with varying Au nanoparticle doping concentrations (0, 0.04 and 0.08 M) that have a thickness of roughly 250 nm. Investigated were the structural and optical characteristics. The films were amorphous to the pure films at the substrate temperature (320 °C), according to X-ray diffraction and remain so even after adding GNPs, because the WO3 structure is amorphous in all samples, whereas the cubic structure of the gold nanoparticles. The morphology of the films was examined using atomic force microscopy (AFM), which showed a decrease in the grain size of the films doped with gold compared to the thin films before the doping process. a UV-Vis spectrophotometer was used to examine the membranes' optical characteristics between the wavelengths of (300-1000) nm. was the optical energy gap of the films (3.23) eV for tungsten oxide film and decreased after adding nanoscale gold to (3.04, 2.95) eV for films doped with different proportions of Au NPs (0.04, 0.08 M), respectively. Hall testing confirms that with 8 (mM) Gold (Au) doping, WO3 material of the n type was obtained with a maximum carrier mobility of 219.92(cm2 /Vs) and conductivity of 6.52 (Ω.cm)-1 . The I-V characteristics of the photovoltaic formed under illumination were determined by measuring the incident power density (100 mW/cm2 ) at varied Au doping levels.