Surface parametric influences on the photocatalytic behaviour of zinc oxide nanoparticles

Abstract

Zinc oxide nanoparticles were chemically synthesised and characterised by UV-DRS spectroscopy, FTIR, scanning electron microscopy with energy-dispersive X-ray diffraction, and X-ray powder diffraction. In order to evaluate the impact of the synthesis process on the structural parameters, Rietveld refinement was done using the GSAS-II programme on experimentally acquired XRD data. ZnO was found to have a hexagonal structure with lattice parameters of a = b =3.247 Å; c = 5.205Å and an average size of about 20-40 nm, as determined by Rietveld refinement of XRD and SEM data. FTIR and EDX analysis was used to confirm the functional group and elemental composition of ZnO NPs. The UV-DRS spectra revealed that the synthesised ZnO had an optical band gap of 3.05 eV. Parametric investigations of the surface morphology of ZnO nanostructures were conducted using the Gwyddion programme. Pseudo-first-order rate kinetics were observed for the photodegradation of two cationic dyes, MB (87.87%) and RhB (74.79%), in the presence of UV light.