Affiliation:
1. State Key Laboratory of Mechanics and Control for Aerospace Structures & Key Laboratory for Intelligent Nano Materials and Devices of Ministry of Education & Institute for Frontier Science & College of Aerospace Engineering Nanjing University of Aeronautics and Astronautics (NUAA) Nanjing China
Abstract
AbstractThe oxidation resistance of yttria‐stabilized zirconia (YSZ) thermal barrier coatings and conductivity of YSZ solid oxide fuel cells are closely related to the diffusion of oxygen ions () in YSZ, but the diffusion behavior in small‐sized YSZ samples under non‐isothermal condition where the temperature gradient () could be significant remaining elusive. Herein, we disclose the previously unrevealed effect of extreme on the self‐diffusion behavior of in both pristine and strained YSZ. It is found that the self‐diffusion coefficient () experiences a nearly one‐fold increase under an extreme around 60 K/Å. The diffusion direction tends to be toward regions of high temperature. Uniaxial stress is revealed to reduce due to the increased activation energy of ions, whereas promotes the self‐diffusion in the stressed system. These results underscore the role of in influencing the self‐diffusion behavior of YSZ, providing a theoretical guideline for examining ceramics serving in extreme environments.