Cold‐cap structure in a slurry‐fed electric melter

Author:

Ferkl Pavel1ORCID,Hrma Pavel2,Kloužek Jaroslav34ORCID,Kruger Albert A.5ORCID,Pokorný Richard34ORCID

Affiliation:

1. Pacific Northwest National Laboratory Richland Washington USA

2. U.S. Department of Energy, AttainX Support Services Contractor to the Office of River Protection Richland Washington USA

3. Laboratory of Inorganic Materials University of Chemistry and Technology Prague Prague Czech Republic

4. Institute of Rock Structure and Mechanics Czech Academy of Sciences Prague Czech Republic

5. U.S. Department of Energy Office of River Protection Richland Washington USA

Abstract

AbstractAs glass batch is charged into an electric melter, a cold cap forms on the glass melt surface. Heat transfer to the cold cap from the molten glass below and the melter atmosphere above determines the melting rate. A mathematical model of the cold cap and the experimental kinetic data of the feed‐to‐glass conversion that were collected for several simulated low‐activity and high‐level waste melter feeds allowed us to develop relationships between the internal structure of the cold cap, its properties, its thickness, and the internal heat transfer. This contribution shows the distribution of major crystalline phases and the cumulative evolution of gases within the cold cap. It also examines the temperature, conversion degree, and heating rate the melter feed is experiencing during the passage through the cold cap and their effects on the cold‐cap bottom temperature and morphology, which are important for the computational fluid dynamics simulations of melters.

Publisher

Wiley

Subject

General Materials Science

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