Characterization of graphite–chromium carbide composites manufactured by spark plasma sintering

Author:

Piñuela‐Noval Juan1,Fernández‐González Daniel1,Suárez Marta1,Díaz Luis Antonio1,Verdeja Luis Felipe2,Fernández Adolfo1

Affiliation:

1. Centro de Investigación en Nanomateriales y Nanotecnología (CINN) Consejo Superior de Investigaciones Científicas (CSIC) Universidad de Oviedo (UO) Principado de Asturias (PA) El Entrego Asturias Spain

2. Departamento de Ciencia de Los Materiales e Ingeniería Metalúrgica Escuela de Minas Energía y Materiales Universidad de Oviedo Calle Independencia Oviedo Asturias Spain

Abstract

AbstractThis manuscript contains an investigation about the influence of the chromium content on the properties of novel graphite–chromium composites obtained by spark plasma sintering (SPS), with great potential application in heat dissipation. Green compacts of 40 mm in diameter were first obtained by uniaxial pressing at 60 MPa, and then the composite was sintered at 1800°C in SPS under vacuum conditions and a pressure of 30 MPa. These sintering conditions involved local liquid phase, which promoted the densification of the composite up to values close to 90%. Different chromium contents were studied, 0, 1, 2, 5, 7, and 10 vol.%, where the best properties (densification, young modulus, electrical conductivity, thermal conductivity, and flexural strength) were obtained in the case of the composite with 7 vol.% Cr: 86.22%, 52.7 GPa, 0.79 MS/m, 264 W/m K, and 38.97 MPa, respectively, measured in the in‐plane direction due to the anisotropic behavior of the composite.

Funder

Ministerio de Ciencia e Innovación

Gobierno del Principado de Asturias

Publisher

Wiley

Subject

Materials Chemistry,Ceramics and Composites

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