Application of factorial model for an optimization of partial replacement of feldspar by talc on the sintering process

Author:

da Silva Robson Couto1ORCID,La Porta Felipe de Almeida2,Silva Graciela Aparecida dos Santos3,Tebcherani Renato Mandalozzo4,Kubaski Evaldo Toniolo1ORCID,Bonfante Estevam Augusto5ORCID,Tebcherani Sergio Mazurek36ORCID

Affiliation:

1. Department of Materials Engineering State University of Ponta Grossa (UEPG) Ponta Grossa Paraná Brazil

2. Laboratory of Nanotechnology and Computational Chemistry Federal University of Technology – Paraná Londrina Paraná Brazil

3. Department of Chemistry State University of Ponta Grossa (UEPG) Ponta Grossa Paraná Brazil

4. Department of Medicine State University of Ponta Grossa (UEPG) Ponta Grossa Paraná Brazil

5. Department of Prosthodontics and Periodontology, Bauru School of Dentistry University of São Paulo Bauru São Paulo Brazil

6. Department of Production Engineering Federal University of Technology – Paraná Ponta Grossa Paraná Brazil

Abstract

AbstractThis research used a factorial model containing two levels and three variables to evaluate the partial substitution of sodium feldspar (albite) by a talc ore found in abundance in the region of Itaiacoca—Brazil. The model can also be used to verify the influence of initial talc particle size, proportion, and sintering threshold temperature on the following physical properties, such as linear shrinkage, water absorption, bulk density, total porosity, and firing color. In this study, the mechanical strength of the compositions was evaluated by the flexural strength test. The factorial model indicated the sintering temperature as the variable that most affects the samples’ densification and the proportion of talc as the variable that changes the firing color. The experiment that used a higher sintering temperature combined with a coarser talc granulometry presented the highest mechanical strength. When more refined granulometry was used, there was the beginning of an overfire process. Water absorption values in the range of .04% and modulus of rupture of 49 MPa were obtained, confirming the talc's effectiveness as a secondary flux agent suitable for the formulation of ceramic bodies.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Wiley

Subject

Materials Chemistry,Marketing,Condensed Matter Physics,Ceramics and Composites

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