Cefazaflur: kinetics of hydrolysis in aqueous solution, acid dissociation constant and alkaline decomposition to fluorescent products

Author:

Irwin Vincent P1,Timoney Richard F1

Affiliation:

1. Department of Pharmaceutical Chemistry, School of Pharmacy, Trinity College, Dublin, Ireland

Abstract

Abstract The values of the pseudo-first order hydrolysis rate constants in the pH range 1 to 10, and the pKa, were determined for cefazaflur in aqueous solution at 37°C and ionic strength 0·2 M. A fluorimetric assay, based on alkaline hydrolysis at 100°C, was also developed for this compound. The results are consistent with previously reported related properties of other monoprotic cephalosporins.

Publisher

Oxford University Press (OUP)

Subject

Pharmaceutical Science,Pharmacology

Reference9 articles.

1. In vitro studies with cefazaflur and other cephalosporins;Actor;J. Antibiot.,1977

2. Fluorimetric determination of ampicillin and cephalexin;Barbhaiya;Br. J. Pharmacol.,1976

3. Fluorimetric determination of cephradine in plasma;Heald;J. Pharm. Sci.,1976

4. Fluorimetric analysis of ampicillin in biological fluids;Jusko;Ibid.,1971

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