Chemoselective light‐induced reactivity of β‐enaminones-Reference-Cited by-同舟云学术

Chemoselective light‐induced reactivity of β‐enaminones

Published:2023-11-27 Issue: Volume: Page:
ISSN:0031-8655
Container-title:Photochemistry and Photobiology
language:en
Short-container-title:Photochem & Photobiology

Author:

Valloli Lakshmy Kannadi¹^ORCID,Manal Kavyasree¹^ORCID,Lewis Brieanna¹,Jockusch Steffen¹^ORCID,Sivaguru Jayaraman¹^ORCID

Affiliation:

1. Department of Chemistry, Center for Photochemical Sciences Bowling Green State University Bowling Green Ohio USA

Abstract

AbstractThe irradiation of β‐enaminones, generated in situ from cyclic 1,3‐diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3‐diketones employed viz., 2‐acetylcyclopentanone and 2‐acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann‐Kon rule.

Publisher

Wiley

Subject

Physical and Theoretical Chemistry,General Medicine,Biochemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1111/php.13889

Reference28 articles.

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